Talatisamine, a C19-diterpenoid alkaloid from Chinese traditional herbal `Chuanwu'

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Talatisamine, a C19-diterpenoid alkaloid from Chinese traditional herbal ‘Chuanwu’

THE TITLE COMPOUND [SYSTEMATIC NAME: (1S,4S,5R,7S,8S,9R,10R,11S,13S,14S,16S,17R)-N-methyl-8,14-dihy-droxy-1,16-tri-meth-oxy-4-(meth-oxy-methyl-ene)aconitane], C(24)H(39)NO(5), was isolated from the roots of Aconitum carmichaelii Debx., which is known as 'Chuanwu' in Chinese traditional herbal medicine. The mol-ecule has an aconitane carbon skeleton with four six-membered rings and two five-memb...

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Crystal structure of sepaconitine, a C19-diterpenoid alkaloid from the roots of Aconitum sinomontanum Nakai

The title compound [systematic name: [(1α,14α,16β)-20-ethyl-8,9,10-trihy-droxy-1,14,16-tri-meth-oxy-aconitan-4-yl 2-amino-benzoate], C30H42N2O8, a natural C19-diterpenoid alkaloid, possesses an aconitane carbon skeleton with four six-membered rings and two five-membered rings. The fused ring system contains two chair, one boat, one twist-boat and two envelope conformations. Intra-molecular N-H⋯...

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Diterpenoid alkaloids from the Chinese traditional herbal "Fuzi" and their cytotoxic activity.

Ten diterpenoid alkaloids, including eight aconitine-type C₁₉-diterpenoid alkaloids and two hetisine-type C₂₀-diterpenoid alkaloids, were isolated from the secondary roots of Aconitum carmichaeli Debx., known as "Fuzi" in Chinese traditional herbal medicine. Their structures were established on the basis of their spectroscopic data and comparison with those of the literature. Among these alkalo...

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Traditional Chinese herbal medicine

Lida Teng, BSc, is a PhD student at the Centre for Pharmacognosy and Phytotherapy, School of Pharmacy, University of London; Debbie Shaw, BSc, is a research scientist at the Medical Toxicology Unit, Guy’s and St Thomas’ Hospital NHS Foundation Trust, London; and Joanne Barnes, PhD, MRPharmS, is associate professor in herbal medicines at the School of Pharmacy, Faculty of Medical and Health Scie...

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Anthriscifolcine A, a C18-diterpenoid alkaloid

The title compound, C(26)H(39)NO(7), which was isolated from Delphinium anthriscifolium var. majus, has a lycoctonine carbon skeleton containing four six-membered rings (A, B, D and E) and three five-membered rings (C, F and G). Rings A, B and E adopt chair conformation, while ring D adopts a boat conformation. Rings C and F adopt envelope conformations.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811044242